Ok, the pro spoke.
Burnt valve is the cause the of the valve failure. The valve burnt most likely from an overheating situation. Any over heating that you remember?
That valve burnt due to the center cylinder being hottest due to design. When it got hot, It at sometime has caused it to hang open thus allowing hot gasses to blow by the valve making the valve head get hot and "Crystalize" then snap!
You can see that the head gasket was allowing gasses blow from cylinder to cylinder (Red Circles) but, not necessarily coolant because it wasn't at the water jackets.
The yellow circle shows a or the location that may have been the hot spot for over heating. That would be on the intake side and it would have been the part that got the hottest.
Advice, Take both heads off have both redone professionally, new valves, new guides, new seats, re-surface, and new gaskets along with new head bolts. If you do that then you won't be doing this again in another 1000 or so miles if you don't.