The offset would be 0 vs stock 38, i.e. your wheels will be out 1.5". I'd don't go with it. I'd look for the same wheels with back spacing no less than 5.5 (http://www.rsracing.com/tech-wheel.html).
If I correctly understand the term, the front wheels are hub centric, the hub diameter is 100 mm (it is possible to install wheels designed for bigger diameter, but not smaller). And there's nothing wrong to install hub centric wheels on the rear (I believe they should be different by the hub cup size, but check if the hub cups are supplied at all).
2001 Isuzu VehiCROSS (build in progress): 4JX1/A340/part time, 2" body lift, front Aisin hubs, rear Aussie Locker, 4.56 gears, OEM rear sway bar disconnect, AirFlow snorkel, cabin air filter
1980 Jeep Cherokee (assembling): 1.5" body lift, TBI, HEI
1987 AMC Eagle: stock